NUI Maynooth

NUI Maynooth ePrints and eTheses Archive

NUIM Library

Investigation of the Electrochemical Behaviour of MWCNTs in the detection of Cr(VI)

Garry, Lynn M. and Alcock, Bernadette E. and Breslin, Carmel B. (2011) Investigation of the Electrochemical Behaviour of MWCNTs in the detection of Cr(VI). ECS Transactions, 41 (27). pp. 1-7. ISSN 1938-5862

[img]PDF - Requires a PDF viewer such as GSview, Xpdf or Adobe Acrobat Reader
220Kb

Abstract

The electrochemical behaviour of a glassy carbon (GC) electrode modified with MWCNTs was investigated and characterised using K3[Fe(CN)6] as a probe. An increase in the electroactive surface area and the rate of electron transfer was observed on sonication of the MWCNTs prior to casting at the GC electrode. The modified electrode was also used in the detection of Cr(VI) in both pH 5.0 and pH 2.0 aqueous solutions. Better detection limits were obtained in the acidic solution.

Additional Information:© The Electrochemical Society, Inc. [year]. All rights reserved. Except as provided under U.S. copyright law, this work may not be reproduced, resold, distributed, or modified without the express permission of The Electrochemical Society (ECS). The archival version of this work was published in ECS Transactions Vol.41 No.27(2011), pp.1-7. http://dx.doi.org/10.1149/1.3692517
Keywords:Electrochemical Behaviour; MWCNTs; detection; Cr(VI);
Subjects:Science & Engineering > Chemistry
ID Code:3773
Deposited By:Dr. Carmel Breslin
Deposited On:27 Jun 2012 16:30
Journal or Publication Title:ECS Transactions
Publisher:Electrochemical Society
Refereed:Yes
URL:http://ecsdl.aip.org/ECST

Repository Staff Only: item control page