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Reactions of 1,4-bis(tetrazole)benzenes: formation of long chain alkyl halides

McGinley, John and Bond, Andrew and Fleming, Adrienne and Kelleher, Fintan and Prajapati, Vipa (2006) Reactions of 1,4-bis(tetrazole)benzenes: formation of long chain alkyl halides. Tetrahedron, 62 (4). pp. 9577-9581.

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Abstract

The reactions of 1,4-bis[2-(tributylstannyl)tetrazol-5-yl]benzene with α,ω-dibromoalkanes were carried out in order to synthesise pendant alkyl halide derivatives of the parent bis-tetrazole. This led to the formation of several alkyl halide derivatives, substituted variously at N1 or N2 on the tetrazole ring. The crystal structures of 1,4-bis[(2-(4-bromobutyl)tetrazol-5-yl)]benzene (2-N,2-N′), 1,4-bis[(2-(4-bromobutyl)tetrazol-5-yl)]benzene (1-N,2-N′) and 1,4-bis[(2-(8-bromooctyl)tetrazol-5-yl)]benzene (2-N,2-N′) are reported. Further discussion involves the structure of 1,4-bis[2-(6-bromohexyl)-2H-tetrazol-5-yl]benzene (2-N,2-N′) previously reported.

Item Type: Article
Keywords: Tetrazole; Organotin; X-ray; Alkyl halide; NMR spectroscopy;
Subjects: Science & Engineering > Chemistry
Item ID: 927
Depositing User: John McGinley
Date Deposited: 13 Mar 2008
Journal or Publication Title: Tetrahedron
Publisher: Elsevier
Refereed: Yes
URI:

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